Try overriding the address on the individual mail itself by adding a call immediately before your deliver line:
mail.delivery_method :smtp, {
address: 'smtp-relay.sendinblue.com',
port: 587,
user_name: 'xxx@xxxx.com',
password: 'xxxxxxx',
authentication: 'plain',
enable_starttls_auto: true
}
mail.deliver!
That can be a permanent fix (it is actually how I do it in my app), but if not the next puzzle would be to determine why the configuration is not being picked up.